Decisions that inherently pose a risk of injury or a hazard to human beings or property should not be made on the basis of this information. 0000001391 00000 n OSHA HazCom compliant labels are made with chemical & solvent resistant materials. 0000002717 00000 n 12 - ECOLOGICAL INFORMATION When properly used or disposed, the Lithium-Thionyl chloride batteries do not present environmental hazard. startxref Partition coefficient: n None known -octanol/water Not applicable unless there is exposure to an electrolyte. 0000006724 00000 n * Exposure to Thionyl Chloride can irritate the nose and throat. 0000008902 00000 n +T�Ϭzz���[��\�M�It��Gh��|����,Bj��,|8�=��o�j� ��J��TW�SU@2�"���։nl�ZU�YxF���Q*�J�%��Ԓ��d��!�H� ��k��Lת$M�2_��г�U_Z U�@=���,��T��ӥ4��{Xf���ܲ�� PM:�7�#�ҬUQ�z�����" xref 0000000016 00000 n Thionyl chloride is primarily used as a chlorinating reagent, with approximately 45,000 tonnes (50,000 short tons) per year being produced during the early 1990s. Applicable part number: GAP-9419-H THAAD KVB . Inhalation of sulfuryl chloride or thionyl chloride vapors can result in pulmonary edema. 0000001311 00000 n 0000002248 00000 n Thionyl Chloride CAS No 7719-09-7 MATERIAL SAFETY DATA SHEET SDS/MSDS. SUPPLEMENTARY SAFETY AND HEALTH DATA: If the battery is broken or leaked the main hazard is the electrolyte. Purification Methods: Crude SOCl2 can be freed from sulfuryl chloride, sulfur monochloride and sulfur dichloride by refluxing it with sulfur and then fractionally distilling twice. Suitable products for Thionyl chloride SOCl 2. Thionyl chlorideRevision Date 14-Feb-2020. [The SOCl2 is converted to SO2 and sulfur chlorides. CDC twenty four seven. Precautionary statement (s) Prevention. It reacts with water to liberate the toxic gases HCl and SO 2 . [Note: Fumes form when exposed to moist air.] SECTION 2- HAZARD(S) IDENTIFICATION Classification: The batteries described in this SDS are hermetically sealed articles. Because all cells and batteries are defined as “articles”,they are exempt from the requirements of the Hazard Communications Standard. 500g. the larynx and bronchi, chemical pneumonitis, and pulmonary edema. 27 0 obj<>stream P264 Wash ... thoroughly after handling. P270 Do not eat, drink or smoke when using this product. Linking to a non-federal website does not constitute an endorsement by CDC or any of its employees of the sponsors or the information and products presented on the website. [Note: Reacts violently with water to form sulfur dioxide & hydrogen chloride. Toxic exposure to fumes of Thionyl Chloride reacting with water may result in a delayed pulmonary response (longer than two weeks) of bronchiolitis Obliterans-inflammation of the bronchioles. 0 For this reason, improper handling of the battery could lead to distortion, leakage, overheating, explosion, fire, or generation of irritating/corrosive gases and cause human injury or equipment trouble. Thionyl chloride is primarily used as a chlorinating reagent, with approximately 45,000 tonnes (50,000 short tons) per year being produced during the early 1990s. Lithium Thionyl Chloride Battery. 0000002795 00000 n 0000005773 00000 n Thionyl chloride is an inorganic compound with the chemical formula SOCl 2. Safety hazards have ranged from mild venting of toxic materials to violent explosions and fires. Thionyl chloride is listed on schedule 3 of the Chemical Weapons Convention and ordering large amounts may draw attention of the authorities. Buy Thionyl Chloride GHS Labels from HCL & clearly identify hazards. 0000003355 00000 n H314 Causes severe skin burns and eye damage. Solubility in other solvents Thionyl Chloride: Decomposes violently on contact with water. Important additional information about respirator selection, Sulfinyl chloride, Sulfur chloride oxide, Sulfurous dichloride, Sulfurous oxychloride, Thionyl dichloride, Colorless to yellow to reddish liquid with a pungent odor like sulfur dioxide. 0000017598 00000 n Thionyl chloride is an inorganic compound with the chemical formula SOCl2. It is a moderately volatile colourless liquid with an unpleasant acrid odour. Saving Lives, Protecting People, The National Institute for Occupational Safety and Health (NIOSH), National Institute for Occupational Safety and Health, A – NIOSH Potential Occupational Carcinogens, B – Thirteen OSHA-Regulated Carcinogens, D – Substances with No Established RELs, E – OSHA Respirator Requirements for Selected Chemicals, G – 1989 Air Contaminants Update Project: Exposure Limits NOT in Effect, Type C & CE – Definitions for Type C and Type CE Respirators, U.S. Department of Health & Human Services. 0000002751 00000 n 0000020267 00000 n Chronic –Overexposure can cause symptoms of non-fibrotic lung injury. Precautionary statement(s ) P261 Avoid breathing vapours. 13 - DISPOSAL CONSIDERATIONS Dispose in accordance with applicable regulations which vary from country to country. Harmful if swallowed. UN1836 Thionyl chloride, Hazard class: 8; Labels: 8-Corrosive material. Not applicable unless there is exposure to an electrolyte. Binary mixtures of these components seem stable, while ternary mixtures result in spontaneously violent reactions. 0000006028 00000 n H314 Causes severe skin burns and eye damage. Thionyl chloride is an inorganic compound with the chemical formula S O Cl 2.It is a moderately volatile colourless liquid with an unpleasant acrid odour. The electrolyte is mainly solution of Lithium chloride (LiCl), and aluminum chloride (AlCl 3) in Thionyl chloride (SOCl 2). 0000004730 00000 n GHS SDS requirements and classification criteria do … Lithium-Thionyl Chloride (Li-SOCl2) Battery 1/6 Document Number: RD-ER-201501-001 Issued date: 3 January 2015 EVE Energy Co., Ltd Safety and Reliability Lab MATERIAL SAFETY… Thionyl chloride is an inorganic acid chloride mainly used as a reagent to prepare carboxylic acid chlorides from carboxylic acids. Thionyl chloride is sold by various chemical suppliers, but due to its hazards it's generally not available to the amateur chemist. Causes gastrointestinal/digestive tract burns. 0000008223 00000 n Emits dense corrosive fumes in moist air. Wash face, hands and any exposed skin thoroughly after handling. You will be subject to the destination website's privacy policy when you follow the link. OSHA Status: The internal component (thionyl chloride) is hazardous under the criteria of the Federal OSHA Hazard Communication Standard 29 CFR 1920.1200. Based on a scenario where the chemical is spilled into an excess of water (at least 5 fold excess of water), half of the maximum theoretical yield of Sulfur Dioxide gas will be created in 0.25 minutes. 0000007494 00000 n Shipping Requirements: Lithium metal batteries and cells are subject to the shipping requirements and exceptions under 49 CFR 173.185. Application Thionyl chloride may be used in the following processes: • To facilitate the synthesis of indenones from 3-hydroxyindanones via dehydroxylation. <<1b2552d1b1366e49b0bd9b0d50bc0452>]>> 0000009613 00000 n Since most reactions using SOCl 2 evolve these gases, they should be performed only in well‐ventilated hoods. Thionyl chloride is widely used to convert carboxylic acids and alcohols to the corresponding acyl chlorides and alkyl chlorides respectively via an internal nucleophilic substitution. ], Water, acids, alkalis, ammonia, chloryl perchlorate Safety considerations of lithium-thionyl chloride cells The use of spirally wound lithium-thionyl chloride (Li-SOCl2) cells is currently limited because of their hazardous behavior. 0000004033 00000 n [Note: Fumes form when exposed to moist air. Precautionary Statements. 0000001174 00000 n ], inhalation, ingestion, skin and/or eye contact, irritation eyes, skin, mucous membrane; eye, skin burns, Centers for Disease Control and Prevention. * Thionyl Chloride can affect you when breathed in. This is a high energy density sealed battery containing (Lithium) and (Thionyl Chloride) materials. May cause respiratory irritation. The Centers for Disease Control and Prevention (CDC) cannot attest to the accuracy of a non-federal website. Thionyl chloride. trailer * Breathing Thionyl Chloride can irritate the lungs causing coughing and/or shortness of breath. Thionyl chloride is primarily used as a chlorinating reagent, with approximately 45,000 tonnes (50,000 short tons) per year being produced during the early 1990s. 0000003279 00000 n 0000005178 00000 n 0000001761 00000 n Toxic exposure to fumes of Thionyl chloride reacting with water may result in delayed pulmonary response, bronchiolitis Oblitereans(inflammmation of the bronchioles). Do not eat, drink or smoke when using this product. It is a moderately volatile colourless liquid with an unpleasant acrid odour. 169 F (76.1111 °C) NIOSH XM5150000 76 °C OU Chemical Safety Data (No longer updated) More details: 79 °C SynQuest M016-4-01: 79 °C Parchem – fine & specialty chemicals 89100: 168-170 F / 760 mmHg (75.5556-76.6667 °C / 760 mmHg) Wikidata Q409171 169 F / 760 mmHg (76.1111 °C / 760 mmHg) Wikidata Q409171 79 °C Sigma-Aldrich SIAL-18438: 75.7 °C / 760 mmHg Kaye & Laby (No longer … Thionyl chloride solution 2.0 M in methylene chloride; CAS Number: 7719-09-7; Linear Formula: Cl2OS; find Sigma-Aldrich-293121 MSDS, related peer-reviewed papers, technical documents, similar products & more at Sigma-Aldrich. The internal component (thionyl chloride) is hazardous under the criteria of the Federal OSHA Hazard Communication Standard 29 CFR 1920.1200. CDC is not responsible for Section 508 compliance (accessibility) on other federal or private website. HAZARD SUMMARY * Thionyl Chloride can affect you when breathed in. thionyl chloride Thionyl dichloride thionyl dichoride; Thionyl dichloride; Show more chemical information. Shop a large selection of products and learn more about Thionyl chloride, 99%, Alfa Aesar. H331 Toxic if inhaled. Thionyl Chloride: 1.635 Not applicable unless there is exposure to an electrolyte. Sulfinyl chloride, Sulfur chloride oxide, Sulfurous dichloride, Sulfurous oxychloride, Thionyl dichloride Colorless to yellow to reddish liquid with a pungent odor like sulfur dioxide. Please strictly observe safety instructions. 0000001570 00000 n The Saft primary Lithium-Thionyl chloride batteries do not contain toxic materials. 5.2 Special hazards arising from the substance or mixture Sulphur oxides, Hydrogen chloride gas Container explosion may occur under fire conditions. 0000003034 00000 n Hazard statement (s) H302 Harmful if swallowed. %%EOF The mixture of thionyl chloride with ethyl acetate in the presence of zinc or iron metal results in an explosively hazardous mixture. 24 0 obj<> endobj Hazard statement(s ) H302 Harmful if swallowed. Signs and symtoms of exposure :Eye and mucous membrane irritation. 1991]. endstream endobj 25 0 obj<. Certain batteries contain small amounts of thionyl chloride, but it's impractical to extract it. 24 29 * Exposure to Thionyl Chloride can irritate the nose and throat. Thionyl chloride reacts vigorously with water to generate gaseous HCl and SO2. 0000005516 00000 n Chronic: Chronic exposure may cause effects similar to those of acute exposure. Its sale is regulated in many places. Thionyl chloride reacts vigorously with water to generate gaseous HCl and SO2. * Thionyl Chloride is a CORROSIVE CHEMICAL and contact can severely irritate and burn the skin and eyes with possible eye damage. %PDF-1.5 %���� Prevention. Use only outdoors or in a well-ventilated area. H332 Harmful if inhaled. Fires may be fought but only from safe fire fighting distance, evacuate all persons from immediate area of fire. * Breathing Thionyl Chloride can irritate the lungs causing 0000021119 00000 n Violently reacts with water to liberate hydrochloric acid and sulfur dioxide [NFPA 10th ed. 5.3 Advice for firefighters Wear self contained breathing apparatus for fire fighting if necessary. Based on a scenario where the chemical is spilled into an excess of water (at least 5 fold excess of water), half of the maximum theoretical yield of Sulfur Dioxide gas will be created in 0.25 … Thionyl chloride should be stored in glass containers at ambient temperature and protected from moisture. 0000000892 00000 n Ingestion: Corrosive. It is toxic, reacts with water, and is also listed under the Chemical Weapons Convention as it may be used for the production of chemical weapons. * Thionyl Chloride is a CORROSIVE CHEMICAL and contact can severely irritate and burn the skin and eyes with possible eye damage. 0000010294 00000 n National Institute for Occupational Safety and Health (NIOSH) Recommended Exposure Level TO THIONYL CHLORIDE-air: ceiling concentration 1 ppm: NIOSH* DHHS #92-100,1992: National Occupational Exposure Survey 1983 ) and ( Thionyl chloride ghs Labels from HCl & clearly identify hazards not contain toxic materials violent... 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For Disease Control and Prevention ( CDC ) can not attest to the amateur chemist small amounts Thionyl... Communication Standard 29 CFR 1920.1200 NFPA 10th ed P261 Avoid breathing vapours Note: Fumes when...